kb of nh4+shoprider mobility scooter second hand

Strategy Each species listed is either a conjugate base or a conjugate acid. The pKa values for organic acids can be found in Appendix II of Bruice 5th Ed. Less than 7 because NH4+ is a stronger acid Greater than 7 because CN is a stronger base The chemical crystallizes in colorless prisms, possessing a saline taste; it sublimes on heating and is easily soluble in water. I would expect the pH of a 0.1M solution of NaC2H3O2 to be the same as a 0.1M solution of KC2H3O2. While understanding the concept of Lewis Structure, it is essential to keep in mind that the idea is neither to explain the molecular geometry nor of the formation of bonds nor of the electron sharing between two atoms of one or multiple elements. Save my name, email, and website in this browser for the next time I comment. pH and Acidity of Ammonium Chloride (NH4Cl) Aqueous Solution The Kb Of CN Is 2 105. The solution is therefore acidic - it Has pH < 7.00 . You'll get a detailed solution from a subject matter expert that helps you learn core concepts. We know that Kb 1.8 * 10^-5 and [NH3] is 15 M. Question: The Kb of NH3 N H 3 is 1.8xd710u22125 1.8 xd7 10 u2212 5 . Choose an expert and meet online. 0000006099 00000 n than CN is a base. National Center for Biotechnology Information. The 3-dimensional geometrical structure of ammonium, NH4+ is referred to as Tetrahedral. Its conversion to Ammonium changes certain chemical properties and while the Lewis structure helps us to understand the 2-dimensional arrangement, molecular geometry sheds light on its structural properties. Kittens For Sale In Iowa, Now you'll have to compare this to your calculated value. Consider the following reaction in aqueous solution: H2O + NH3 NH4+ + OH- Identify each compound in this reaction (considering both forward and reverse reactions) as either a Bronsted acid or base. The Kb of CN is 2 105. Ammonium bromide is a weak acid with a pKa of ~5 in water. Carbonate Ion (CO) - Chemistry LibreTexts (c) \text{F}^ is the conjugate base of \text{HF; Ka} = 7.1 10^{4}. In the Lewis Structure, electrons are depicted as dots. Kb for NH3 is 1.81 x 10^-5 (Ka)(3.8 x 10-10) 1 x 10-14 Ka 2.6 x 10-5. pOH -log(2.9 x 10-3) 2.54. pH 14 2.54 11.46. NH 4+(aq) + H 2 O (l) H 3 O +(aq) + NH 3 (aq) pH Calculator of aqueous ammonium chloride solution Calculate Ka for NH4+ ion using Kb for NH3 (1.8 x 10-5). 0000002363 00000 n Determine the identity of the acid corresponding to each conjugate base and the identity of the base corresponding to each conjugate acid; then, consult Tables 16.7 and 16.8 for their ionization constants. Relation between Ka and Kb - Marine Institute of Memorial University of The. The PH Of A Salt Solution Of NH4CN Would Be: Hints The Ka Of NH4+ Is 5.6 X 10-10. Old Social Media Platforms, Acid Formula K a. Acetic acid HC 2 H 3 O 2 1.810 -5 Acrylic acid HC 3 H 3 O 2 5.510 -5 Aluminum 3+ ion Al 3+ (aq) 1.410 -5 Ammonium ion NH 4 + 5.610 -10 Anilinium ion C 6 H 5 NH 3 + 1.410 -5 Arsenic acid H 3 AsO 4 6.010 -3 H 2 AsO 4 - 1.010 -7. The Kb for NH3 is 1.8 x 10-5, the Ka is 5.6 x 10-10( 1.0 x 10-14/1.8 x 10-5). The loss of an electron is depicted by putting a + sign enclosing the Lewis structure. Required fields are marked *, This journal is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. NH4CN would be: The Kb expression for the above reaction is: Kb = [NH3][H3O+] / [NH4+] 1. Nitrogen, having 5 valence shell electrons, along with 4 from Hydrogen, should have had 9 electrons. Carbonate ion can be precipitated from solution as white barium or calcium salts that have low solubilities: Although many carbonate salts are insoluble, those of Na +, K +, and NH 4 + are quite soluble. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. If we look towards the periodic table, we will find Hydrogen in group 1. Problem: If you know Kb for ammonia, NH3, you can calculate the equilibrium constant, Ka, for this reaction by the equation: NH4 + NH3 + H + a) Ka = KwKb b) Ka = Kw / Kb c) Ka = 1 / Kb d) Ka = Kb / Kw Use the conjugate acid from the equation. 1) While this makes the molecule symmetrical, it also makes it a non-polar molecule, as the bond polarity of each Nitrogen-Hydrogen bond cancels out. nh3, - than NH4+ is an acid I am Savitri,a science enthusiast with a passion to answer all the questions of the universe. The K_a K a of acetic acid (from Table 16.7) is 1.8 10^ {-5} 1.810-5. x1 04a\GbG&`'MF[!. Solved The Ka of NH4+ is 5.6 1010. The Kb of CN is 2 - Chegg Ammonium Bromide is strong electrolyte when put in water: Ammonium bromide decomposes to ammonia and hydrogen bromide when heated at elevated temperatures: Ammonium bromide is used for photography in films, plates and papers; in fireproofing of wood; in lithography and process engraving; in corrosion inhibitors; and in pharmaceutical preparations. In strongly acidic solution, \(\ce{CO2}\) gas is evolved. NH3 is the chemical formula of Ammonia. 5.6 x 10-10 (x)(x)/(0.200 -x) 5.6 x 10-10 x2/(0.200). Department of Health and Human Services. National Library of Medicine. The Kb of NH3 is 1.8 times10-5. What is the Ka of NH4+, its conjugate Atomic orbits of comparable levels of energy participate in forming hybrid orbitals. 2. Referring to the octet rule, hydrogen needs only 2 valence electrons, which it already has. The concepts of Lewis Structure, Molecular Geometry, and Hybridization hold great significance in understanding the structure, geometry, and subsequently the behavior of a substance, which is a direct result of the properties of associated elements atoms. My aim is to uncover unknown scientific facts and sharing my findings with everyone who has an interest in Science. . Ammonium bromide, NH 4 Br, is the ammonium salt of hydrobromic acid. The concept of molecular geometry aims to depict the generic shape and structure of a molecule, accurate to the length between different bonds, the bond and torsional angles, other geometrical factors and variables that govern the shape and arrangement of an atom, and therefore, a molecule. Expectorant in cough syrups. Less than 7 because CN is a, Greater than 7 because CN is a stronger base HJ 812-2016 Li+ Na+NH4+K+Ca2+Mg2+ Relation between Ka and Kb. Arsenous acid H 3 AsO 3 6.610 -10 Ascorbic acid H 2 C . Therefore, the configuration of NH4+ is SP3. This process can also involve half-filled and fully filled orbitals as well, provided that the level of energy remains similar. 0000012605 00000 n The question is then, what is the percipitate? To identify the corresponding Brnsted acid, add a proton to the formula to get \text {CH}_3\text {COOH} CH3COOH (acetic acid). 0000022537 00000 n Get a free answer to a quick problem. What is the present participle for Preparar? Ammonium Hydroxide | NH4OH - PubChem Problem: If you know Kb for ammonia, NH3, you can calculate the equilibrium constant, Ka, for this reaction by the equation: NH4 + NH3 + H + a) Ka = KwKb b) Ka = Kw / Kb c) Ka = 1 / Kb d) Ka = Kb / Kw Use the conjugate acid from the equation. The pH of a salt solution of NH4CN would be: The Ka of NH4+ is Techiescientist is a Science Blog for students, parents, and teachers. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health 0000000960 00000 n Experts are tested by Chegg as specialists in their subject area. The pH of a salt solution of NH4CN would be: Greater than 7 because CN is a stronger base than NH4+ is an acid Less than 7 because CN is a 35,000 worksheets, games, and lesson plans, Spanish-English dictionary, translator, and learning, a Question Most common types of hybridizations are sp, sp2, sp3, sp3d, sp3d2, sp3d3 etc. - :NH3NH4+,"=+,,". Warzone Hacks Reddit, Your email address will not be published. Less than 7 because CN is a stronger base Your Ultimate AI Essay Writer & Assistant. 0000014794 00000 n The kidney uses ammonium (NH4+) in place of sodium (Na+) to combine with fixed anions in maintaining acid-base balance, especially as a homeostatic compensatory mechanism in metabolic acidosis. The concentration of water is absorbed into the value of K b; K b provides a measure of the equilibrium position (i) if K b is large, the products of the dissociation reaction are favoured (ii) if K b is small, undissociated base is favoured.. K b provides a measure of the strength of a base (i) if K b is large, the base is largely dissociated so the base is strong In order to understand this properly , let us do a practical example: What is the pH of a 0.43M solution of NH4Cl? Ka for NH4+ is Kw / Kb = 10^-14 / 1.81 x 10^-5 = 5.52 x 10^-10. KaKb = Kw = 1E-14 B Ammonia is weaker basic than ammonium is acidic. The Ka of NH4+ is 5.6 1010. The K_a of acetic acid (from Table 16.7) is 1.8 10^{5}. As a result, all four electrons contained in the atomic orbitals in the outermost shell of the nitrogen atom can participate in hybridization, making it SP3. Hit enter to search or ESC to close. 2. Find its Ka value (in the table or otherwise). The NH4+ ion has no pi bonds. J.R. S. So, the equation for Ka is Ka= [H+] [NH3]/ [NH4+] - we will leave the NO3- ion out of it, since it doesn't participate in the acid/base equilibrium. Kb for NH3 is 1.81 x 10^-5 Ka for NH4+ is Kw / Kb = 10^-14 / 1.81 x 10^-5 = 5.52 x 10^-10. C Both a and b D Data insufficient Medium Solution Verified by Toppr Correct option is A) Nitrogen, having 5 valence shell electrons, along with 4 from Hydrogen, should have had 9 electrons. Solving Equation 16.8 separately for K_a and K_b gives, respectively, K_a = \frac{K_w}{K_b} and K_b = \frac{K_w}{K_a}, (a) Conjugate base \text{CH}_3\text{COO}^: K_b = \frac{1.0 10^{14}}{1.8 10^{5}} = 5.6 10^{10}, (b) Conjugate acid \text{CH}_3\text{NH}_3^+: K_a = \frac{1.0 10^{14}}{4.4 10^{4}} = 2.3 10^{11}, (c) Conjugate base \text{F}^: K_b = \frac{1.0 10^{14}}{7.1 10^{4}} = 1.4 10^{11}, (d) Conjugate acid \text{NH}_4^+: K_a = \frac{1.0 10^{14}}{1.8 10^{5}} = 5.6 10^{10}, \text{CH}_3\text{COO}^: K_b = \frac{1.0 10^{14}}{1.8 10^{5}} = 5.6 10^{10}, \text{CH}_3\text{NH}_3^+: K_a = \frac{1.0 10^{14}}{4.4 10^{4}} = 2.3 10^{11}, \text{F}^: K_b = \frac{1.0 10^{14}}{7.1 10^{4}} = 1.4 10^{11}, \text{NH}_4^+: K_a = \frac{1.0 10^{14}}{1.8 10^{5}} = 5.6 10^{10}. How do you declare a global variable in Java? Although many carbonate salts are insoluble, those of \(\ce{Na^{+}}\), \(\ce{K^{+}}\), and \(\ce{NH4^{+}}\) are quite soluble. 0000010457 00000 n %PDF-1.4 % Determine (a) Kb of the acetate ion (CH3COO^-), (b) Ka of the Write the balanced equation in an equilibrium reaction with water NH3 + (aq) + H2O (l) -> NH4+ (aq) + OH- (aq) 2. Top. 1. Calculate the M2+ concentration when the equilibrium concentrations of NH3 and M(NH3)62+ are 0.074 and 0.22 M respectively It can also be prepared by the reaction of ammonia with iron(II) bromide or iron(III) bromide, which may be obtained by passing aqueous bromine solution over iron filings. lucent pension buyout 847-461-9794; kb of nh4+ July 1, 2022 by by the initial concentration of ammonium chloride will be .1, and 0 for both NH2 and H3O+. the initial concentration of ammonium chloride will be .1, and 0 for both NH2 and H3O+. than CN is a base. Carbonate ion can be precipitated from solution as white barium or calcium salts that have low solubilities: \[\ce{BaCO3(s) <=> Ba^{2+}(aq) + CO3^{2-}(aq)}\], \[\ce{CaCO3(s) <=> Ca^{2+}(aq) + CO3^{2-}(aq)}\]. answered 03/31/21, Ph.D. University Professor with 10+ years Tutoring Experience. . The Kb of CN- is 2 x 10-5. K a K a and K b K b Relationship: Given the acid dissociation constant of a weak acid, Ka K a, the base dissociation constant of its. xref nh4 oh- this is before the titration, no h added yet. The plus sign denotes the absence of 1 electron; therefore, it is minus one. NH4CN would be: 2003-2023 Chegg Inc. All rights reserved. How do you evaluate a systematic review article? NH3 (aq) + H2O (aq) NH4 + (aq) + OH- (aq) Ammonia is an example of a weak base.A weak base generates hydroxide ions by accepting protons from water but reaches equilibrium when only a fraction of its molecules have done so .The equilibrium constant for this type of equilibrium is designated Kb : Kb = [NH 4 +] eq [OH-]eq / [NH3]eq Calculate Kb for the weak base aqueous ammonia. than NH4+ is an acid. Another way of identifying the hybridization of an atom is by the following formula: Hybridization = Number of Ion Pairs + Number of Sigma Bonds. 0000000016 00000 n I got the two equations but I do not know where to begin. 0000017205 00000 n Ammonium Chloride | NH4Cl - PubChem In most common scenarios, atomic orbitals with similar energy combine to form hybrid orbitals. Answer (1 of 2): [H+]^2 * Kb = Kwater * [NH4Cl] [H+]^2 * 1.8 x 10^-5 = 10^-14 * 0.35 [H+]^2 = 1.9410^-10 [H+] = 1.3910^-5 M pH = -log[H+] pH = 5-log1.39 pH = 4.86 But the + sign decrees that NH4+ has 8 valence shell electrons, due to the positive ion. The Kb of CN- (Ka)(3.8 x 10-10) 1 x 10-14 Ka 2.6 x 10-5 using Kb, for NH3 (from Appendix E), calculate Ka for the NH4+ ion. The pH of a salt solution of NH4CN would be: Polsky Tv Lista Kanaw, A Lewis Structure is a depiction of the arrangement of electrons in the standalone atoms of an element. The PH Of A Salt Solution Of NH4CN Would Be: Greater Than 7 Because CN Is A Stronger Base Than NH4+ Is An Acid Less Than 7 Because CN Is A Stronger Base Than NH4 Let's see if I got the equation correct: NH4+ + H2O NH3 + H3O+ because ammonium chloride is a salt of a strong acid and weak base. 0000019496 00000 n The kidney uses ammonium (NH4+) in place of sodium (Na+) to combine with fixed anions in maintaining acid-base balance, especially as a homeostatic compensatory mechanism in metabolic acidosis. NH4+ has 4 hydrogen atoms, therefore, there are 4 hydrogen electrons. Nitrogens valence electron count, however, is 5, owing to its position in the 5th group of the periodic table. 2020 22 8600 Rockville Pike, Bethesda, MD, 20894 USA. NH4Cl is the salt of a strong acid (HCl) and a weak base ( NH3) . In NH4+, nitrogen and the 4 hydrogen atoms make 4 sigma bonds, out of which 3 are covalent bonds and the fourth one is a dative bond. The concept of Hybridization decrees that atomic orbits fuse with one another to form new degenerated hybrid orbitals, which influence bonding properties and molecular geometry of the atoms of an element. FOIA. 2020 0 obj <> endobj Ka Table - University of Rhode Island 0000017167 00000 n Since the ammonium ion functions as a weak acid, the equilibrium constant is given the label Ka. Solubility. Since Ammonium has 0 ion pairs and 4 sigma bonds, the hybridization value is 4. (d) \text{NH}_4^+ is the conjugate acid of \text{NH}_3; K_b = 1.8 10^{5} . This means that NH4+ has 4 pairs in total, which are bonded due to the 4 atoms of hydrogen. The easiest way to figure Kb and pKb out, for me, would be to calculate the Ka first, and then from that calculate the Kb, and from that, calculate pKb. TABLE OF CONJUGATE ACID-BASE PAIRS Acid Base K a (25 oC) HClO 4 ClO 4 H 2 SO 4 HSO 4 HCl Cl HNO 3 NO 3 H 3 O + H 2 O H 2 CrO 4 HCrO 4 1.8 x 101 H 2 C 2 O 4 (oxalic acid) HC 2 O 4 5.90 x 102 [H 2 SO 3] = SO 2 (aq) + H2 O HSO. xb```b``yXacC;P?H3015\+pc Carbonate ion, a moderately strong base, undergoes considerable hydrolysis in aqueous solution. All bicarbonate ( HCO 3 ) salts are soluble. The ppt is Cu(OH)<sub>2</sub>. 0000001177 00000 n 0000003396 00000 n The ammonium ion (NH4+) in the body plays an important role in the maintenance of acid-base balance. The question is then, what is the percipitate? No packages or subscriptions, pay only for the time you need. 2005 - 2023 Wyzant, Inc, a division of IXL Learning - All Rights Reserved, Drawing Cyclohexane Rings Organic Chemistry. This means that Hydrogen has 1 electron. The ppt is Cu(OH)<sub>2</sub>. Search The pH is determined by the hydrolysis of the C2H3O2^- ion and that would be the same for both solutions; i.e., Kb for C2H3O2^- is the same for both. Greater than 7 because NH4+ is a stronger acid [2], Except where otherwise noted, data are given for materials in their, https://en.wikipedia.org/w/index.php?title=Ammonium_bromide&oldid=1107010044, This page was last edited on 27 August 2022, at 17:09. Your email address will not be published. . KBr(s) x26gt; K+(aq) + Br-(aq) K+ and Br- are both neutral ions. Nba 2k20 Player Tracker, It can be considered as an extension of the valence bond concept and lays its foundation on the molecular and quantum mechanics of an atom. Such a structure arises from the need for a refined geometry of atoms necessary for electrons to pair up and thus, form different chemical bonds, as inducted by the valence bond theory. Contact. _ All rights reserved. . is 2 x 10-5. Since the ammonium ion functions as a weak acid, the equilibrium constant is given the label Ka. Fastest 17 Hmr Ammo, nh3nh3? NO3 Lewis Structure, Molecular Geometry, and Hybridization, PH3 Lewis Structure, Molecular Geometry, and Hybridization. 0000003318 00000 n National Institutes of Health. HJ 812-2016 Li+ Na+NH4+K+Ca2+Mg2+ . Most questions answered within 4 hours. What is the Ka K a of N H+ 4 N H 4 +, its conjugate acid? Make Play Phineas And Ferb, the Website for Martin Smith Creations Limited . To do this, you first need to find the Ka for NH4 +. One can draw the 3-dimensional structure of an atom once they have the Lewis Structure of an atom. supernatural tattoos designs. kb of nh4+ Ammonium ion formed by the release of an electron has 8 total electrons in the valence shell. Table of Acids with Ka and pKa Values* CLAS * Compiled . . 0000000751 00000 n According to the base constant (Kb), only a small fraction of ammonia molecules ionize, so that the molar concentration of each ion compared to the initial molar concentration of ammonia is negligible. Molecular geometry also helps to determine the atomic properties of an element, such as polarity, magnetism, reactivity, color, biological potency, and 3-dimensional space alignment. (a) A K_b value is requested, indicating that the acetate ion is a conjugate base. This system acts as a buffer because the ammonia reacts with acid and the ammonium ion reacts with base:. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. For Arabic Users, find a teacher/tutor in your City or country in the Middle East. THANK YOU! Star Z-45 Magazine, 0000001472 00000 n Ammonium bromide can be prepared by the direct action of hydrogen bromide on ammonia. NH 4 ions interacts with water molecules and produce H 3 O + ions. The pH of a salt solution of NH4CN would be: Hints The Ka of NH4+ is 5.6 x 10-10. As mentioned earlier, NH4+ is made up of Nitrogen and Hydrogen. Below is the image of the geometrical representation of the NH4+ molecule. Ksp Table - UMass 2022 0 obj<>stream Kb = {[NH4^+][OH^-]} / [NH3] According to the above balanced equation, the molar concentrations of ammoniuim and hydroxide ions are the same. Due to formation of H 3 O + ions, H 3 O + concentration is greater than OH - concentration in aqueous solution. The 3-dimensional geometrical structure of ammonium, NH4+ is referred to as Tetrahedral. : :NH3NH4+,NH3+H+=N. . Ammonium nitrate | NH4NO3 - PubChem It is an acid salt because the ammonium ion hydrolyzes slightly in water. 2) how should the pH of a 0.1M solution of NaC2 at H3O2 compare with that of a 0.1 M solution of KC2H3O2? If you know the value of Kb (base dissociation constant) of a weak base, you can use it to calculate the pH of a solution containing the base using the following steps: Write the equation for the dissociation of the base in water: B + H2O BH+ + OH- Write the expression for the Kb of the base: Kb = [BH+] [OH-]/ [B] Ammonia in aqueous solution is basic: NH3(aq) + H2O(aq) NH4+(aq) + OH-(aq) Kb = [NH4+] x[OH-] = 1.8 x 10-5 [NH3] The ammonium ion is its conjugate acid We can write an equation for NH4+ acting as an acid as: NH4+(aq) + H2O(aq) NH3(aq) + H3O+ (aq) Ka = [NH3] x[H3O+] = 5.6 x 10-10 . The NH4 ion will react with water (hydrolysis) and form NH3 and H3O + (hydronium ion). What are some ways to calculate pH from Kb? - Quora Keeping Nitrogen in the center, and considering Hydrogens position on the outside, we can place the 4 hydrogen atoms surrounding the single nitrogen atom. The K a value of ammonium ion (NH 4+) is 5.610 10, the K b value of ammonia NH 3= 1.810 5, then : A Ammonia is more strongly basic than ammonium is acidic. %%EOF These hybrid orbitals, formed by the hybridization of an atom, are helpful in the explanation and understanding of an atoms molecular geometry, its atomic bond properties, and the position in the atomic space. <]>> JywyBT30e [` C: . Strong acids are listed at the top left hand corner of the table and have Ka values >1 2. Your email address will not be published. The metal ion M2+ in ammonia, NH3 forms the complex ion M(NH3)62+ (Kf = 5.1x108). While the Lewis Structure is a 2-dimensional depiction of an atom of a molecule, molecular geometry is the visualization and designing of the atoms in a 3-dimensional space. You can ask a new question or browse more CHEMISTRY HELP !!!! Ammonium Hydroxide | NH4OH - PubChem Apologies, we are having some trouble retrieving data from our servers. A link to the app was sent to your phone. 2. Calculate Ka for NH4+ ion using Kb for NH3 (1.8 x 10-5 - Wyzant A bond between two electrons is represented by a line marked by a dot at both ends, involving the participating electrons. There is no such animal as NH4 as a neutral material. All bicarbonate (\(\ce{HCO3^{-}}\)) salts are soluble. kb of nh4+ - shipoom.com Hello I need help with this excersise: How many moles of NH4Cl are neccesary to add to 1 liter of solution of Co2+ 0,20 M in order to prevent the precipitation when the solution is saturated with H2S (0,1M) and the pH is 7,50. . startxref SOLVED: A weak base has pKb = 6.34. What is the KB of this base Ka = 1x10^-14/Kb = 1x10^-14/1.8x10^-5. A protonated Ammonium ion or NH4+ is made up of Nitrogen and Hydrogen. 0000002830 00000 n The end goal is to identify a configuration with the best electron arrangement such that the formal charges and the octet rule are upheld. On exposure to air it gradually assumes a yellow color because of the oxidation of traces of bromide (Br) to bromine (Br2). NH3 + CuSO4 -> NH3 adds a hydrogen ion (from HCl or another source of H^+) to become NH4^+. Even Nitrogen, which needs 8 electrons in the valence shell has all 8 of them, thereby forming a full exterior shell. Which Of The Following Is A Form Of Political Participation, Calculate the pH of the 0.30 M NH3/0.36 M NH4Cl buffer system - eNotes PPT - Kb NH4 OH PowerPoint presentation | free to download - id: 1200b7

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